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Silanetriols as Powerful Starting Materials for Selective Condensation to Bulky POSS Cages
[Image: see text] Controlled condensation reactions of tertiary silanetriols CH(3)(CH(2))(n)(CH(3))(2)CSi(OH)(3) (1b–f; n = 1–5) in the presence of trifluoroacetic acid and the hydrolysis of CH(3)(CH(2))(6)(CH(3))(2)CSiCl(3) (3) lead to the selective formation of the corresponding disiloxane tetrols...
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| Publicado no: | Organometallics |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2014
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4276717/ https://ncbi.nlm.nih.gov/pubmed/25550679 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om5010918 |
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