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Synthesis, structure and π-delocalization of a phosphaalkenyl based neutral PNP-pincer

Preparation, characterization and structural properties of a novel bis-phosphaalkenyl based PNP-pincer are reported. In this pincer the π-system is delocalized over all three donor sites, which was demonstrated with DFT calculations, UV–Vis measurements and structural findings. As a consequence of t...

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Detalhes bibliográficos
Main Authors: Orthaber, Andreas, Belaj, Ferdinand, Pietschnig, Rudolf
Formato: Artigo
Idioma:Inglês
Publicado em: Elsevier Sequoia [etc.] 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3171142/
https://ncbi.nlm.nih.gov/pubmed/21966023
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ica.2011.02.078
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