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P–C bond formation via P–H addition of a fluoroaryl phosphinic acid to ketones
The synthesis, structure and reactivity of the fluoroaryl phosphinic acid HF(4)C(6)–P(O)HOH is reported and compared to a sterically comparable yet non-fluorinated analog with similar size. The fluoroaryl phosphinic acid undergoes reversible P–H addition to the carbonyl functionality of ketones unde...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Elsevier Sequoia Sa
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2954306/ https://ncbi.nlm.nih.gov/pubmed/21072125 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jfluchem.2010.07.008 |
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