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P–C bond formation via P–H addition of a fluoroaryl phosphinic acid to ketones

The synthesis, structure and reactivity of the fluoroaryl phosphinic acid HF(4)C(6)–P(O)HOH is reported and compared to a sterically comparable yet non-fluorinated analog with similar size. The fluoroaryl phosphinic acid undergoes reversible P–H addition to the carbonyl functionality of ketones unde...

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Autori principali: Orthaber, Andreas, Albering, Jörg H., Belaj, Ferdinand, Pietschnig, Rudolf
Natura: Artigo
Lingua:Inglês
Pubblicazione: Elsevier Sequoia Sa 2010
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2954306/
https://ncbi.nlm.nih.gov/pubmed/21072125
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jfluchem.2010.07.008
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