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Aerobic radical multifunctionalization of alkenes using tert-butyl nitrite and water

Water induces a change in the product of radical multifunctionalization reactions of aliphatic alkenes involving an sp(3) C–H functionalization by an 1,5-hydrogen shift using tert-butyl nitrite and molecular oxygen. The reaction without water, reported previously, gives nitrated γ-lactols, whereas t...

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Bibliografske podrobnosti
Main Authors: Hirose, Daisuke, Taniguchi, Tsuyoshi
Format: Artigo
Jezik:Inglês
Izdano: Beilstein-Institut 2013
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3778400/
https://ncbi.nlm.nih.gov/pubmed/24062832
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.196
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