Difunctionalization of alkenes with iodine and tert-butyl hydroperoxide (TBHP) at room temperature for the synthesis of 1-(tert-butylperoxy)-2-iodoethanes

We developed a direct vicinal difunctionalization of alkenes with iodine and TBHP at room temperature. This iodination and peroxidation in a one-pot synthesis produces 1-(tert-butylperoxy)-2-iodoethanes, which are inaccessible through conventional synthetic methods. This method generates multiple ra...

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Publicat a:Beilstein J Org Chem
Autors principals: Wang, Hao, Chen, Cui, Liu, Weibing, Zhu, Zhibo
Format: Artigo
Idioma:Inglês
Publicat: Beilstein-Institut 2017
Matèries:
Letter
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5629392/
https://ncbi.nlm.nih.gov/pubmed/29062424
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.13.200
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