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Rhodium-catalyzed enantioselective cyclopropanation of electron deficient alkenes
The rhodium-catalyzed reaction of electron-deficient alkenes with substituted aryldiazoacetates and vinyldiazoacetates results in highly stereoselective cyclopropanations. With adamantylglycine derived catalyst Rh(2)(S-TCPTAD)(4), high asymmetric induction (up to 98% ee) can be obtained with a range...
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| 主要な著者: | , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2013
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3773518/ https://ncbi.nlm.nih.gov/pubmed/24049630 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC50425E |
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