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Rhodium-catalyzed enantioselective cyclopropanation of electron deficient alkenes
The rhodium-catalyzed reaction of electron-deficient alkenes with substituted aryldiazoacetates and vinyldiazoacetates results in highly stereoselective cyclopropanations. With adamantylglycine derived catalyst Rh(2)(S-TCPTAD)(4), high asymmetric induction (up to 98% ee) can be obtained with a range...
Bewaard in:
| Hoofdauteurs: | , , , , |
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| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2013
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3773518/ https://ncbi.nlm.nih.gov/pubmed/24049630 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC50425E |
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