Llwytho...
Total Synthesis of (+)-Trienomycins A and F via C-C Bond-Forming Hydrogenation and Transfer Hydrogenation
The triene-containing C17-benzene ansamycins trienomycins A and F are prepared in 16 steps (longest linear sequence, LLS) and 28 total steps. The C11-C13 stereotriad is prepared via enantioselective ruthenium catalyzed alcohol CH-syn-crotylation followed by chelation-controlled carbonyl dienylation....
Wedi'i Gadw mewn:
| Prif Awduron: | , |
|---|---|
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
2013
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3757526/ https://ncbi.nlm.nih.gov/pubmed/23862627 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4061273 |
| Tagiau: |
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