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Total Synthesis of 6-Deoxyerythronolide B via C-C Bond-Forming Transfer Hydrogenation
The 14-membered macrolide 6-deoxyerythronolide B is prepared in 14 steps (longest linear sequence) and 20 total steps. Two different methods for alcohol CH-crotylation via transfer hydrogenation are deployed for the first time in target-oriented synthesis. Enyne metathesis is used to form the 14-mem...
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| Hlavní autoři: | , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2013
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3625983/ https://ncbi.nlm.nih.gov/pubmed/23464668 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4008722 |
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