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Reaction between peroxynitrite and boronates: EPR spin-trapping, HPLC analyses, and quantum mechanical study of the free radical pathway
Recently we showed that peroxynitrite (ONOO(−)) reacts directly and rapidly with aromatic and aliphatic boronic acids (k ≈ 10(6) M(−1)s(−1)). Product analyses and substrate consumption data indicated that ONOO(−) reacts stoichiometrically with boronates, yielding the corresponding phenols as the maj...
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| Main Authors: | , , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2011
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3743543/ https://ncbi.nlm.nih.gov/pubmed/21434648 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/tx100439a |
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