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Reversible hydrogen transfer reactions of cysteine thiyl radicals in peptides: the conversion of cysteine into dehydroalanine and alanine, and of alanine into dehydroalanine
The photodissociation of disulfide bonds in model peptides containing Ala and Ala-d(3) generates a series of photoproducts following the generation of a CysS(•) thiyl radical pair. These photoproducts include transformations of Cys to dehydroalanine (Dha) and Ala, as well as Ala to Dha. Intramolecul...
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| Главные авторы: | , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2011
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3736842/ https://ncbi.nlm.nih.gov/pubmed/21895001 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp2070453 |
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