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Reversible intramolecular hydrogen transfer between cysteine thiyl radicals and glycine and alanine in model peptides: absolute rate constants derived from pulse radiolysis and laser flash photolysis

The intramolecular reaction of cysteine thiyl radicals with peptide and protein (α)C-H bonds represents a potential mechanism for irreversible protein oxidation. Here, we have measured absolute rate constants for these reversible hydrogen transfer reactions by means of pulse radiolysis and laser fla...

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Bibliografski detalji
Glavni autori: Nauser, Thomas, Casi, Giulio, Koppenol, Willem H., Schöneich, Christian
Format: Artigo
Jezik:Inglês
Izdano: 2008
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2662404/
https://ncbi.nlm.nih.gov/pubmed/18973367
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp805133u
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