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Cysteine residues as catalysts for covalent peptide and protein modification: a role for thiyl radicals?
Cysteine thiyl radicals engage in reversible intramolecular hydrogen transfer reactions with amino acid residues in peptides and proteins. These reactions can be experimentally demonstrated through covalent H/D exchange when experiments are carried out in D(2)O. To this end, hydrogen transfer reacti...
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| Autor principal: | |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3691957/ https://ncbi.nlm.nih.gov/pubmed/21936798 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1042/BST0391254 |
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