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Intramolecular hydrogen transfer reactions of thiyl radicals from glutathione: formation of carbon-centered radical at Glu, Cys and Gly

Glutathione thiyl radicals (GS(•)) were generated in H(2)O and D(2)O by either exposure of GSH to AAPH(), photoirradiation of GSH in the presence of acetone, or photoirradiation of GSSG. Detailed interpretation of the fragmentation pathways of deuterated GSH and GSH-derivatives during mass spectrome...

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Bibliografische gegevens
Hoofdauteurs: Mozziconacci, Olivier, Williams, Todd D., Schöneich, Christian
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2012
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3736831/
https://ncbi.nlm.nih.gov/pubmed/22712461
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/tx3000494
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