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Synthesis of Cyclopentenimines from N-Allyl Ynamides via a Tandem Aza-Claisen Rearrangement–Carbocyclization Sequence

[Image: see text] We describe here details of our investigations into Pd-catalyzed and thermal aza-Claisen–carbocyclizations of N-allyl ynamides to prepare a variety of α,β-unsaturated cyclopentenimines. The nature of the ynamide electron withdrawing group and β-substituent plays critical roles in t...

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Main Authors: Wang, Xiao-Na, Winston-McPherson, Gabrielle N., Walton, Mary C., Zhang, Yu, Hsung, Richard P., DeKorver, Kyle A.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2013
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3732456/
https://ncbi.nlm.nih.gov/pubmed/23718841
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo400960e
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