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An Efficient Synthesis of de novo Imidates via Aza-Claisen Rearrangements of N-Allyl Ynamides

A novel thermal 3-aza-Claisen rearrangement of N-allyl ynamides for the synthesis of α-allyl imidates is described. Also, a sequential aza-Claisen, Pd-catalyzed Overman rearrangement is described for the synthesis of azapine-2-ones.

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Bibliografische gegevens
Hoofdauteurs: DeKorver, Kyle A., North, Troy D., Hsung, Richard P.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2010
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3027154/
https://ncbi.nlm.nih.gov/pubmed/21278848
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0030-1258544
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