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An Intramolecular [2 + 2] Cycloaddition of Ketenimines via Palladium-Catalyzed Rearrangements of N-Allyl-Ynamides

[Image: see text] A cascade of Pd-catalyzed N-to-C allyl transfer–intramolecular ketenimine–[2 + 2] cycloadditions of N-allyl ynamides is described. This tandem sequence is highly stereoselective and the [2 + 2] cycloaddition could be rendered in a crossed or fused manner depending on alkene substit...

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Detalhes bibliográficos
Main Authors: DeKorver, Kyle A., Hsung, Richard P., Song, Wang-Ze, Wang, Xiao-Na, Walton, Mary C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3426664/
https://ncbi.nlm.nih.gov/pubmed/22667819
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol3013233
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