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Carbocyclization Cascades of Allyl Ketenimines via Aza-Claisen Rearrangements of N-Phosphoryl-N-Allyl-Ynamides

[Image: see text] A series of carbocyclization cascades of allyl ketenimines initiated through a thermal aza-Claisen rearrangement of N-phosphoryl-N-allyl ynamides is described. Interceptions of the cationic intermediate via Meerwein-Wagner rearrangements and polyene-type cyclizations en route to fu...

詳細記述

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書誌詳細
主要な著者: DeKorver, Kyle A., Wang, Xiao-Na, Walton, Mary C., Hsung, Richard P.
フォーマット: Artigo
言語:Inglês
出版事項: 2012
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3321125/
https://ncbi.nlm.nih.gov/pubmed/22414252
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol300366e
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