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Photoredox Activation for the Direct β-Arylation of Ketones and Aldehydes
The direct β-activation of saturated aldehydes and ketones has long been an elusive transformation. We found that photoredox catalysis in combination with organocatalysis can lead to the transient generation of 5π-electron β-enaminyl radicals from ketones and aldehydes that rapidly couple with cyano...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3723331/ https://ncbi.nlm.nih.gov/pubmed/23539600 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1232993 |
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