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Direct β-Functionalization of Cyclic Ketones with Aryl Ketones via the Merger of Photoredox and Organocatalysis

The direct β-coupling of cyclic ketones with aryl ketones has been achieved via the synergistic combination of photoredox catalysis and organocatalysis. Diaryl oxymethyl or aryl–alkyl oxymethyl radicals, transiently generated via single-electron reduction of ketone precursors, readily merge with β-e...

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Hlavní autoři: Petronijević, Filip R., Nappi, Manuel, MacMillan, David W. C.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3934322/
https://ncbi.nlm.nih.gov/pubmed/24237366
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja410478a
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