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Solid-phase peptide synthesis and solid-phase fragment coupling mediated by isonitriles
The synthesis of polypeptides on solid phase via mediation by isonitriles is described. The acyl donor is a thioacid, which presumably reacts with the isonitrile to generate a thio-formimidate carboxylate mixed anhydride intermediate. Applications of this chemistry to reiterative solid-phase peptide...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3718127/ https://ncbi.nlm.nih.gov/pubmed/23821753 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1310431110 |
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