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Base-Catalyzed Direct Aldolization of α-Alkyl-α-Hydroxy Trialkyl Phosphonoacetates
[Image: see text] Catalytic direct aldol addition of α-hydroxy trialkyl phosphonacetates to aldehydes affords α-hydroxy-β-phosphonyloxy ester products. The fully substituted glycolate enolate intermediate is generated in situ under mild conditions via [1,2]-phosphonate-phosphate rearrangement. High...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3685868/ https://ncbi.nlm.nih.gov/pubmed/22474004 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201200559 |
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