Загрузка...
A Computational Study of the Origin of Stereoinduction in NHC-Catalyzed Annulation Reactions of α,β-Unsaturated Acyl Azoliums
The origin of stereoselectivity of NHC-catalyzed annulation reactions of ynals and stable enols was studied with Density Functional Theory. The data suggest that the C-C bond formation is the stereo-determining step. Only the deprotonated pathway (containing an oxy anion and overall neutral species)...
Сохранить в:
| Главные авторы: | , , |
|---|---|
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2012
|
| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3655779/ https://ncbi.nlm.nih.gov/pubmed/23687566 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC20331F |
| Метки: |
Добавить метку
Нет меток, Требуется 1-ая метка записи!
|