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The effect of the N-mesityl group in NHC-catalyzed reactions
The majority of N-heterocyclic carbene catalyzed reactions of α-functionalized aldehydes, including annulations, oxidations, and redox reactions, occur more rapidly with N-mesityl substituted NHCs. In many cases, no reaction occurs with NHCs lacking ortho-substituted aromatics. By careful competitio...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3655724/ https://ncbi.nlm.nih.gov/pubmed/23687565 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C1SC00397F |
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