Hydrogen bonding effects on the reactivity of [X-Fe(III)–O–Fe(IV)=O] (X = OH, F) complexes towards C–H bond cleavage

Complexes 1-OH and 1-F are related complexes that share similar [X–Fe(III)–O–Fe(IV)=O](3+) core structures with a total spin S of ½, which arises from antiferromagnetic coupling of an S = 5/2 Fe(III)-X site and an S = 2 Fe(IV)=O site. EXAFS analysis shows that 1-F has a nearly linear Fe(III)–O–Fe(IV...

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Hauptverfasser: Xue, Genqiang, Geng, Caiyun, Ye, Shengfa, Fiedler, Adam T., Neese, Frank, Que, Lawrence
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2013
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3632308/
https://ncbi.nlm.nih.gov/pubmed/23496330
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic3027896
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