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Biosynthesis, isolation, and NMR analysis of leukotriene A epoxides: substrate chirality as a determinant of the cis or trans epoxide configuration

Leukotriene (LT)A(4) and closely related allylic epoxides are pivotal intermediates in lipoxygenase (LOX) pathways to bioactive lipid mediators that include the leukotrienes, lipoxins, eoxins, resolvins, and protectins. Although the structure and stereochemistry of the 5-LOX product LTA(4) is establ...

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Autori principali: Jin, Jing, Zheng, Yuxiang, Boeglin, William E., Brash, Alan R.
Natura: Artigo
Lingua:Inglês
Pubblicazione: The American Society for Biochemistry and Molecular Biology 2013
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3617949/
https://ncbi.nlm.nih.gov/pubmed/23242647
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1194/jlr.M033746
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