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Electronic communication across diamagnetic metal bridges: a homoleptic gallium(III) complex of a redox-active diarylamido-based ligand and its oxidized derivatives

Complexes with cations of the type [Ga(L)(2)](n+) where L = bis(4-methyl-2-(1H-pyrazol-1-yl)phenyl)amido and n = 1, 2, 3 have been prepared and structurally characterized. The electronic properties of each were probed by electrochemical and spectroscopic means and were interpreted with the aid of DF...

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Autors principals: Liddle, Brendan J., Wanniarachchi, Sarath, Hewage, Jeewantha S., Lindeman, Sergey V., Bennett, Brian, Gardinier, James R.
Format: Artigo
Idioma:Inglês
Publicat: 2012
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3601749/
https://ncbi.nlm.nih.gov/pubmed/23163736
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic301437f
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