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Redox activity of a dissymmetric ligand bridging divalent ytter-bium and reactive nickel fragments†

The reaction of a reactive nickel dimethyl 1 bearing a redox-active, dissymmetric ligand, which is obtained by deprotonation of 2-pyrimidin-2-yl-1H-benzimidazole (Hbimpm) with a divalent lanthanide complex, Cp*(2)Yb(OEt(2)), affords an unprecedented, trimeric 2 with C(sp(3))–C(sp(3)) bond formation...

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Detalhes bibliográficos
Publicado no:Inorg Chem Front
Main Authors: Wang, Ding, Tricoire, Maxime, Cemortan, Valeriu, Moutet, Jules, Nocton, Grégory
Formato: Artigo
Idioma:Inglês
Publicado em: 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7116723/
https://ncbi.nlm.nih.gov/pubmed/33575034
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/D0QI00952K
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