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Tuning the Stability of Pd(IV) Intermediates Using a Redox Non-innocent Ligand Combined with an Organolanthanide Fragment
[Image: see text] The unique combination of a divalent organolanthanide fragment, Cp*(2)Yb, with bipyrimidine (bipym) and a palladium bis-alkyl fragment, PdMe(2), allows the rapid formation and stabilization of a Pd(IV) tris-alkyl moiety after oxidative addition with MeI. The crucial role of the org...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2017
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5553092/ https://ncbi.nlm.nih.gov/pubmed/28741942 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b05634 |
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