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Synthesis of Binucleating Macrocycles and their Nickel(II) Hydroxo- and Cyano-Bridged Complexes with Divalent Ions: Anatomical Variation of Ligand Features
The planar NNN-pincer complexes [M(II)(pyN (Me)(2))(OH)](1−) (M(II) = Ni, Cu) fix CO(2) in η(1)-OCO(2)H complexes; results for the copper system are described. Mn(II), Fe(II), Co(II), and Zn(II) behave differently, forming [M(II)(pyN(2)(Me))(2)](2−) with N(4)O(2) coordination. Incorporation of the N...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3483644/ https://ncbi.nlm.nih.gov/pubmed/23030366 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic301506x |
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