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A Simple Homoleptic Gallium(I) Olefin Complex: Mimicking Transition‐Metal Chemistry at a Main‐Group Metal?
The earth‐metal olefin complex [Ga(I)(COD)(2)](+)[Al(OR(F))(4)](−) (COD=1,5‐cyclooctadiene; R(F)=C(CF(3))(3)) constitutes the first homoleptic olefin complex of any main‐group metal accessible as a bulk compound. It is straight forward to prepare in good yield and constitutes an olefin complex of a...
Shranjeno v:
| izdano v: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
John Wiley and Sons Inc.
2020
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7820946/ https://ncbi.nlm.nih.gov/pubmed/32959513 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202011466 |
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