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Enantioselective Synthesis of Atropisomeric Benzamides through Peptide-Catalyzed Bromination
We report the enantioselective synthesis of atropisomeric benzamides employing catalytic electrophilic aromatic substitution reactions involving bromination. The catalyst is a simple tetrapeptide bearing a tertiary amine that may function as a Brønsted base. A series of tri- and dibrominations are a...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3596792/ https://ncbi.nlm.nih.gov/pubmed/23410090 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja400082x |
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