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Spontaneous transfer of chirality in an atropisomerically enriched two-axis system

Perhaps the most well-recognized stereogenic elements within chiral molecules are sp(3)-hybridized carbon atoms possessing four different substituents. However, axes of chirality may also exist about bonds with hindered barriers of rotation, leading to stereoisomers known as atropisomers.(1) Underst...

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Autors principals: Barrett, Kimberly T., Metrano, Anthony J., Rablen, Paul R., Miller, Scott J.
Format: Artigo
Idioma:Inglês
Publicat: 2014
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4008667/
https://ncbi.nlm.nih.gov/pubmed/24747399
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nature13189
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