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Mechanistic Studies of Wacker-Type Amidocyclization of Alkenes Catalyzed by (IMes)Pd(TFA)(2)(H(2)O): Kinetic and Stereochemical Implications of Proton Transfer()
The stereochemical course of the amidopalladation of alkenes has important implications for the development of enantioselective Pd-catalyzed “Wacker-type” oxidative amination of alkenes. We have recently shown that the addition of base (Na(2)CO(3)) can alter the stereochemical course of amidopallada...
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| Main Authors: | , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2012
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3586306/ https://ncbi.nlm.nih.gov/pubmed/23157332 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo302266t |
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