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Reconciling the Stereochemical Course of Nucleopalladation with the Development of Enantioselective Wacker-Type Cyclizations

A novel stereochemical substrate probe was used to assess the factors that affect the stereochemical course of nucleopalladation (cis vs. trans) in the context of an enantioselective Wacker-type reaction. We demonstrate that the enantioselectivity correlates directly with the nucleopalladation pathw...

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Bibliografiska uppgifter
Huvudupphovsmän: Weinstein, Adam B., Stahl, Shannon S.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2012
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC3492954/
https://ncbi.nlm.nih.gov/pubmed/23074039
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201206702
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