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Reconciling the Stereochemical Course of Nucleopalladation with the Development of Enantioselective Wacker-Type Cyclizations
A novel stereochemical substrate probe was used to assess the factors that affect the stereochemical course of nucleopalladation (cis vs. trans) in the context of an enantioselective Wacker-type reaction. We demonstrate that the enantioselectivity correlates directly with the nucleopalladation pathw...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2012
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3492954/ https://ncbi.nlm.nih.gov/pubmed/23074039 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201206702 |
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