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Probing the Mechanism of 1,4-Conjugate Elimination Reactions Catalyzed by Terpene Synthases
The reaction mechanisms of (E)-β-farnesene synthase (EBFS) and isoprene synthase (ISPS), enzymes that catalyze a formal regioespecific 1,4-conjugate elimination of hydrogen-diphosphate from (E, E)-farnesyl and dimethylallyl diphosphate (FDP and DMADP) to generate the semiochemicals (E)-β-farnesene a...
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| Main Authors: | , , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2012
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3530649/ https://ncbi.nlm.nih.gov/pubmed/23214943 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja311022s |
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