Probing the Mechanism of 1,4-Conjugate Elimination Reactions Catalyzed by Terpene Synthases

The reaction mechanisms of (E)-β-farnesene synthase (EBFS) and isoprene synthase (ISPS), enzymes that catalyze a formal regioespecific 1,4-conjugate elimination of hydrogen-diphosphate from (E, E)-farnesyl and dimethylallyl diphosphate (FDP and DMADP) to generate the semiochemicals (E)-β-farnesene a...

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Huvudupphovsmän: Faraldos, Juan A., Gonzalez, Veronica, Li, Amang, Yu, Fanglei, Köksal, Mustafa, Christianson, David W., Allemann, Rudolf K.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2012
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Article
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC3530649/
https://ncbi.nlm.nih.gov/pubmed/23214943
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja311022s
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