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Total Synthesis of Auripyrone A Using a Tandem Non-Aldol Aldol-Paterson Aldol Process as a Key Step
A tandem non-aldol aldol-Paterson aldol generates the polypropionate 12 from the epoxy alcohol 8 and the ketone 9 in only two steps and 74% overall yield as a single diastereomer, due to double stereodifferentiation, where the stereoinduction from the enolate and the α-methyl substituent of the alde...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3523744/ https://ncbi.nlm.nih.gov/pubmed/19824033 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200904607 |
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