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Total Synthesis of Auripyrone B Using a Non-Aldol Aldol-Cuprate Opening Process
[Image: see text] A non-aldol aldol-cuprate opening generates the polypropionate 11 from the epoxy ether 14 in 8 steps as a single diastereomer. A highly stereoselective aldol reaction of 8 with 9 gives the aldol product 7 in high yield and excellent diastereoselectivity, due to double stereodiffere...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4099051/ https://ncbi.nlm.nih.gov/pubmed/20499854 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100985n |
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