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Palladium-Catalyzed Allylic Alkylation of Carboxylic Acid Derivatives: N-Acyloxazolinones as Ester Enolate Equivalents
A general asymmetric allylic alkylation of ester enolate equivalents at the carboxylic acid oxidation state is reported. N-Acylbenzoxazolinone-derived enol carbonates are synthesized in good yield and employed in the palladium-catalyzed alkylation reaction. Good yields (up to 99%) and enantioselecti...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3517038/ https://ncbi.nlm.nih.gov/pubmed/22095749 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201105801 |
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