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Practical Method for the Cu-Mediated Trifluoromethylation of Arylboronic Acids with CF(3) Radicals Derived from NaSO(2)CF(3) and tert-Butyl Hydroperoxide (TBHP)
[Image: see text] A mild and practical protocol for the copper-mediated trifluoromethylation of aryl and heteroaryl boronic acids using NaSO(2)CF(3) (Langlois’ reagent) and TBHP is described. The reaction proceeds at room temperature under ambient conditions, and the products can be readily purified...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3513340/ https://ncbi.nlm.nih.gov/pubmed/22984900 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol3022726 |
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