Practical Method for the Cu-Mediated Trifluoromethylation of Arylboronic Acids with CF(3) Radicals Derived from NaSO(2)CF(3) and tert-Butyl Hydroperoxide (TBHP)

[Image: see text] A mild and practical protocol for the copper-mediated trifluoromethylation of aryl and heteroaryl boronic acids using NaSO(2)CF(3) (Langlois’ reagent) and TBHP is described. The reaction proceeds at room temperature under ambient conditions, and the products can be readily purified...

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Main Authors: Ye, Yingda, Künzi, Stefan A., Sanford, Melanie S.
Format: Artigo
Sprog:Inglês
Udgivet: 2012
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3513340/
https://ncbi.nlm.nih.gov/pubmed/22984900
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol3022726
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