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Synthesis and ring openings of cinnamate-derived N-unfunctionalised aziridines
tert-Butyl cinnamates are aziridinated with high trans-selectivity by an N–N ylide generated in situ from N-methylmorpholine and O-diphenylphosphinyl hydroxylamine. The resulting N-unfunctionalised aziridines are shown to be versatile synthetic building blocks that undergo highly selective ring-open...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Beilstein-Institut
2012
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3511008/ https://ncbi.nlm.nih.gov/pubmed/23209508 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.199 |
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