Development of Enantioselective Synthetic Routes to (–)-Kinamycin F and (–)-Lomaiviticin Aglycon

The development of enantioselective synthetic routes to (–)-kinamycin F (9) and (–)-lomaiviticin aglycon (6) is described. The diazotetrahydrobenzo[b]fluorene (diazofluorene) functional group of the targets was prepared by fluoride-mediated coupling of a β-trimethylsilylmethyl-α,β-unsaturated ketone...

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Bibliographic Details
Main Authors: Woo, Christina M., Gholap, Shivajirao L., Lu, Liang, Kaneko, Miho, Li, Zhenwu, Ravikumar, P. C., Herzon, Seth B.
Format: Artigo
Language:Inglês
Published: 2012
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3505684/
https://ncbi.nlm.nih.gov/pubmed/23030272
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja307497h
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