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Mechanistic Studies on CymD: A Tryptophan Reverse N-Prenyltransferase()
The prenyltransferase CymD catalyzes the reverse N-prenylation of tryptophan using dimethyllallyl diphosphate (DMAPP) in the biosynthesis of the cyclic peptides cyclomarin and cyclomarazine. The mechanism is of interest since a non-nucleophilic indole nitrogen must be alkylated in this process. Thre...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3475536/ https://ncbi.nlm.nih.gov/pubmed/22935004 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi3009054 |
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