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On the proposed structures and stereocontrolled synthesis of the cephalosporolides
The synthesis of four candidate stereoisomers of cephalosporolide H is described, made possible by a zinc-chelation strategy for controlling the stereochemistry of oxygenated 5,5-spiroketals. The same strategy likewise enables the first stereocontrolled synthesis of cephalosporolide E, which is typi...
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| Huvudupphovsmän: | , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
Beilstein-Institut
2012
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3458751/ https://ncbi.nlm.nih.gov/pubmed/23019461 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.146 |
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