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Total synthesis of the proposed structure of astakolactin
The first total synthesis of the proposed structure of astakolactin, a sesterterpene metabolite isolated from the marine sponge Cacospongia scalaris, has been achieved, mainly featuring Johnson–Claisen rearrangement, asymmetric Mukaiyama aldol reaction and MNBA-mediated lactonization.
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| 出版年: | Beilstein J Org Chem |
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| 主要な著者: | , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
Beilstein-Institut
2014
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4222296/ https://ncbi.nlm.nih.gov/pubmed/25383112 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.252 |
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