Total synthesis of the proposed structure of astakolactin

The first total synthesis of the proposed structure of astakolactin, a sesterterpene metabolite isolated from the marine sponge Cacospongia scalaris, has been achieved, mainly featuring Johnson–Claisen rearrangement, asymmetric Mukaiyama aldol reaction and MNBA-mediated lactonization.

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Bibliografiske detaljer
Udgivet i:Beilstein J Org Chem
Main Authors: Tonoi, Takayuki, Mameda, Keisuke, Fujishiro, Moe, Yoshinaga, Yutaka, Shiina, Isamu
Format: Artigo
Sprog:Inglês
Udgivet: Beilstein-Institut 2014
Fag:
Full Research Paper
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4222296/
https://ncbi.nlm.nih.gov/pubmed/25383112
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.252
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