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Freeze-frame inhibitor captures acetylcholinesterase in a unique conformation

The 1,3-dipolar cycloaddition reaction between unactivated azides and acetylenes proceeds exceedingly slowly at room temperature. However, considerable rate acceleration is observed when this reaction occurs inside the active center gorge of acetylcholinesterase (AChE) between certain azide and acet...

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Detalhes bibliográficos
Main Authors: Bourne, Yves, Kolb, Hartmuth C., Radić, Zoran, Sharpless, K. Barry, Taylor, Palmer, Marchot, Pascale
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2004
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC341740/
https://ncbi.nlm.nih.gov/pubmed/14757816
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0308206100
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